N-(Ferrocenylmethyl)dodecan-1-amine
نویسندگان
چکیده
The title compound, [Fe(C(5)H(5))(C(18)H(32)N)], was synthesized by the amination of ferrocenecarbaldehyde. In the complex, the two cyclo-penta-dienyl (Cp) rings are almost parallel with a dihedral angle of 1.36 (8)°, and are separated by a centroid-centroid distance of 3.299 (2) Å. In the crystal, adjacent mol-ecules are linked into a one-dimensional supra-molecular structure via weak C-H⋯π inter-actions between the Cp ring H atom and the Cp ring.
منابع مشابه
Synthesis, characterization and crystal structures of boron-containing intermediates in the reductive amination of ferrocenecarboxaldehyde to a bis(ferrocenylmethyl) amine
Reaction of ferrocenecarboxaldehyde with aqueous methylamine leads to [(methylimino)methyl]ferrocene, which is reduced to N(ferrocenylmethyl)-N-methylamine by NaBH4. This amine reacts with ferrocenecarboxaldehyde and NaCNBH3 to give the tertiary ammonium salt, di(N-(ferrocenylmethyl))-N-methylammonium cyanoborohydride. Hydrolysis of the NaCNBH3 reaction mixture produces the free amine, di(N-(fe...
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